Kobushi Kuroi

A young woman of average height with a full figure and long red hair. As Black Fist, she wears a little crown on her head, also a black suit, which resembles Black Fist - a famous thief in London 100 years ago. Her appearance is almost simillar to her sister. She fell in love with Rindo Urushiba after he saved her.

A young thief, having the invisibility ability. She is a thief known for her misdeeds announce in advance. She is a very good boxer and loves fighting policemen mixing her invisibility ability and her boxing skill. She has a great ego and hates losing a fight. After being saved by Rindo, she adores him deeply, calling him her "Prince" and starts staying with Rinka, much to her dismay.

Ayumu Oozora

A son of one of the most outspoken people against Espers and everything they stand for.

He has the power of Precognition, but he can only see two seconds into the future. He is a middle school student with aspirations to be a member of Congress, like his mother.

The Professor

Kyotaro's adoptive and Minami's father, who leads the group that is letting the glowing fish roam free.

His ESP powers allow him to create all types of illusions. He has a burn scar on the left side of his face that he keeps hidden behind an illusion.

Ren Jomaku

She appears in the second part of the manga series after the time skip. Her ESP can form blocks of ice that can be placed on any material. She is the target of the terrorists because of her "lock space" power. Ren is average height, her hair color is black along with black eyes. She wears glasses with a brown (or gold) frame. She is an ESP high school student that dreams of love. She was a shut-in since she locked herself at her home after her ESP awakened. Her mentality can be weak, but she is determined to become strong. At times she is clumsy and fantasizes about romance even in dangerous situations. She was Ayumu's classmate in middle school. Her ESP awoke in the summer, and after that her classmates started to ostracize and even bully her. She thought that Ayumu was her friend, but Ayumu was already an esper at the time. Because Ayumu was a little afraid of Ren's power and had his own problems to deal with, he decided not to help her. Unable to deal with the pressure, Ren decided to lock herself in at home. Ren hates Ayumu for "betraying" her, but after meeting each other again their relationship had gradually improved.

Her story began when her skirt was stuck in a train door, on the first day of 'school', which is in fact the ESP Academy . Then Zeusu, who was still a stranger, used his ESP and broke a small part of the door, freeing her skirt. Ren didn't say thanks because she was taken in by his good looks and had started to fantasize about having a romance with him. She realized that Zeusu was enrolled in the same ESP academy, and being obsessed as she was, constantly looked around for him even during the opening ceremony at school. All of a sudden, terrorists attacked the school while she was in bathroom. Panicking, she accidentally used her freezing ESP power and froze the water in the sink, getting her own hand stuck in the ice. She managed to free her hand with warm water, but then one of the terrorists noticed her and started to advance on her in a menacing manner, intending sexual assault. She freaked out and froze the terrorist within a block of ice and ran. The other terrorists now saw her as a danger and gave chase.

Eventually she found herself in a dead end, with the only exit being blocked by a locked thick metal door. Just as the terrorists encroached, a man-sized circular portion of the door fell out, revealing Zeusu, who beckoned at Ren to come through. She did just that, and Ren sealed the door in again. The two hurried away just in time, before a fire-wielding terrorist ESPer blasted down the entire door. Zeusu, with Ren in tow, ran up to the roof of the building, the terrorists hot in pursuit. They were greeted on the roof by Yoda, who had taken off the head of his panda costume. Shocked by his queer appearance, Ren froze Yoda, thinking that he was an alien. Dismayed, Yoda berated Ren for foiling his plans, of which Zeusu is also a part of, to lure the terrorists up onto the roof and take care of them there. With his hands stuck in a block of ice now though, Yoda could only watch as the terrorists burst out onto the roof. Outnumbered and inexperienced, Ren was quickly taken down by the terrorists, who started to give her a beating for causing them trouble. Zeusu shielded her from the blows using his own body. Panicking as she saw the source of her infatuation getting bloodied and bruised, Ren released the full extent of her power and froze all the terrorists in a huge tower of ice blocks. At that instant, there was the silhouette of a glowing fish, just that it was shaped like a shark and not a normal fish like the others. At the same time, a glowing black sphere appeared to surround the vicinity, and just for that second it seemed as if time itself had frozen. Cryokinesis: She can creates ice blocks on anything or throw them suddenly. The ice blocks she creates can be a trap for somebody or gigantic normal ice blocks. She can also freeze water by touching it. Lock Space: She can creates a black, locked space that can stop time and other things. The locked space appears around her or her target, and tons of ice blocks appears around the target(s) or even lock them inside. At first she can't control it but, she mangages to controls it so Zeusu won't die. Oozora, Ayumu : He was her friend but he then ignored her when her powers manifested. Thus causing a rift between them. After her kidnapping, their relationship improved when he tries to help her and make amends. Zeusu Tetsuya : Her bodyguard and her crush, because he rescued her.

Kyotaro Azuma

Kyotaro Azuma (東 京太郎 Azuma Kyōtarō) is the male protagonist of Tokyo ESP. He is the supposed "emissary of justice" for ESPers and works under the guise of "Crow Head". His parents worked on the research project that brought about the Glowing Fish in the first place. Azuma is average height, slightly taller than Rinka with long black hair, thick sideburns and dark brown eyes with lashes on the underside. He has a regular build but is supposedly very strong, as he was able to lift Rinka and her father, who is quite big, and knock out a plethora of gangsters with a baseball bat.

Azuma is an eccentric character, virtually always smiling and sometimes a bit slow on the uptake. He is very caring, however, especially towards Rinka. His personality is always calm and collected.  When faced with a tough situation such as when Black fist robbed the museum.  He would take hits to protect Rinka and thinks of strategies to get out of tight spots. Azuma also has a strong sense of justice which resulted in the creation of "Crow Head", a persona he uses when fighting evil in Tokyo. Kyotaro firmly believes in the responsibility that comes with great power, a symbol of his heroic actions. He also refuses to hit girls, causing him to rely on Rinka in situations with female villains. Azuma's parents were archaeologists who brought him along to a small country off the coast of Russia during one of their excavations. His parents were close friends with the Professor and his wife. During the excavation, they uncovered "the Ark" mentioned within the Bible.

Rinka Urushiba: They first met six months before the manga starts when she saved him from a bunch of bullies. She didn't even acknowledge him and he never got the chance to thank her, but he said he always considered her his hero. They met again later while chasing the shinning fish. Afterwards they have developed a deep bond and have even gone on a "date" (to catch an esper) and later he says he want to go on a real date with her. At the end of part one they can be seen embracing each other, and in part two they are holding hands while beginning their secret mission that made them disappear for a few months. They both In Love in Ending. Uncovering the Ark led to the Professor, his wife, and Azuma's parents gaining ESP. In part one, He meets up with Rinka Urushiba on a bike and follows her to the shinning fish. Afterwards he talks her into becoming a hero with him and becoming his partner. Even making a white crow head mask for Rinka, which she rejected. They then search for clues on the shinning fish when they saw Peggi, a flying penguin getting kidnapped along with a young girl.

Rinka Urushiba

Rinka Urushiba (漆葉 リンカ Urushiba Rinka) is the main protagonist of the first arc of Tokyo ESP. She lived a normal - albeit low class - life with her ex-police officer father until the interception by the Glowing Fish and self-proclaimed ESP vigilante Kyotaro Azuma. Since then she has become his assistant in the acquisition of other ESPers.  Rinka is average height, with her distinguished dirty blonde hair that she received from her American mother and burgundy eyes. She has a full figure and pale skin with a mole below her left eye. Despite her dainty appearance she is extremely agile and proficient at melee attacks, specifically her signature Psy-kick. When her esp is "activated" her hair turns white, which is how she got her nickname, White Girl.

Rinka, although determined to live a normal life, helps Azuma reluctantly with his ESPer excursions. She keeps a level head in situations and her persistence is to be admired. Few times Rinka was ever depressed, but she was brought out of it by Azuma, her father or Yoda. She also doesn't seem to mind ridicule too much, or even hesitate to mock someone. Rinka awakens one day to find herself falling through the floor to the apartment below her's naked. Frightened, she runs up the stairs but cannot dial her father since the phone falls through her fingers. She manages to leave as she begins sinking again. Then, Azuma appears and covers her with a towel, telling her to calm down. She remembers previously leaving school on her bike but being sidetracked by a flying penguin. She chases it to Tokyo Sky Tree, where she encounters a gleeful Azuma cheering at a spectacle. He points out to her the Glowing Fish flying through the sky which the flying penguin is chasing, which no other person seems able to see. A fish floats down and enters her body and she passes out. Elsewhere, Rindo is describing to another officer his own experience with the fish as he listens to Rinka's message. He runs to her and all cars - rather, all metallic objects - follow behind and around him. Rinka manages to get dressed and states she's going to a hospital. Her father calls and says that he's looking for her, but the cars have compressed around him. She spots the cluster as well as everyone else in the nearby area. Rinka calls for her father but he can't hear her. Azuma infers that knocking him unconscious could negate the power, as Rinka couldn't use it when she was asleep. Rinka argues that as a former policeman he was extremely durable and they didn't have the time to wait for him to fall asleep. She remembers all the times he has been there for her and decides to act now.

Azuma says that if she fails it would hurt but Rinka runs into the fray, getting noticed by bystanders and giving her the nickname White Girl based on her white hair. She jumps into the car cluster and phases through everything, giving her father her Skull-Crushing Psy-kick, knocking him out. Azuma jumps in as the cars begin to collapse and congratulates her, grabbing hold of her and her father and teleporting them both away from the scene. Rinko notes with amazement how they suddenly appeared in Ikebukuro and Azuma labels his power "teleportation". He introduces himself to her as an ESPer. Rinka remains with her father at home until he awakens. She remembers how, after rescuing them, Azuma claimed to not know anything about the Glowing Fish. She decides that, despite the events that occurred hitherto, she is going to work, because they need the money. At the diner she works at Azuma is there, startling her. Soon after police come by asking the owner if she has seen the robber Black Fist who continuously slips into places unnoticed, beats up all guards and steals without ever being seen. They were on edge there because of the art gallery next door. Their only clue to Black Fist is that he/she disappears with smoke, leading Rinka to believe Azuma is the criminal. Physical Permeation: Rinka, by the Glowing Fish, has been given the ability to phase through any object. She can also choose what object she can go through, such as how she can go through a wall but keep all her clothes on and even take others with her as long as they are touching. Like every other ESPer, when not making a conscious effort all things pass through her. A downside to this ability is that she is unable to pass through living things like people or animals. Skull-Crushing Psy-kick: Rinka's signature move in the beginning of Tokyo ESP, which involves a kick with extreme momentum (from falling a great distance) towards a person. It is strong enough to knock out her father, who has a brick-wall type build, but is not lethal. Thousand-Armed Counter: Rinka's signature combat style. Due to training from Yoda, Rinka possesses extremely honed reflexes, and can also sense her opponent's chi to predict their movements, making their attacks simple to counter. She can also use chi sensing to fight while blinded or with her eyes closed, see through illusions, and sense enemies' positions.